{"id":2069,"date":"2017-07-05T15:00:25","date_gmt":"2017-07-05T18:00:25","guid":{"rendered":"https:\/\/www.nachodelatorre.com.ar\/mosconi\/?p=2069"},"modified":"2017-07-05T15:00:25","modified_gmt":"2017-07-05T18:00:25","slug":"materiales-que-copian-al-pulpo-para-ser-adhesivos-bajo-el-agua","status":"publish","type":"post","link":"https:\/\/www.fie.undef.edu.ar\/ceptm\/?p=2069","title":{"rendered":"Materiales que copian al pulpo para ser adhesivos bajo el agua"},"content":{"rendered":"<p>La ciencia siempre ha tratado de usar los ejemplos de la naturaleza para inspirarse en la soluci\u00f3n de retos tecnol\u00f3gicos, como poner a la gente en el cielo (aves) o para el tratamiento de enfermedades (plantas). Ahora, investigadores de Corea del Sur han encontrado en el pulpo la respuesta a la pregunta: \u00bfC\u00f3mo hacer algo adhesivo bajo el agua? Esto es relevante pues dicho adhesivo se puede utilizar para desarrollar una nueva generaci\u00f3n de cinta adhesiva m\u00e9dica para ligar heridas, as\u00ed como vendas capaces de pegarse en piel mojada.<!--more--><\/p>\n<p>Adhesion strategies that rely on mechanical interlocking or molecular attractions between surfaces can suffer when coming into contact with liquids<sup><a id=\"ref-link-1\" title=\"Lee, H., Lee, B. P. &amp; Messersmith, P. B. A reversible wet\/dry adhesive inspired by mussels and geckos. Nature 448, 338\u2013341 (2007)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref1\">1<\/a>, <a id=\"ref-link-2\" title=\"Isrealachvili, J. Intermolecular and Surface Forces (Academic, 1991)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref2\">2<\/a><\/sup>. Thus far, artificial wet and dry adhesives have included hierarchical mushroom-shaped or porous structures that allow suction or capillarity<sup><a id=\"ref-link-3\" title=\"Dirks, J.-H. &amp; Federle, W. Fluid-based adhesion in insects\u2014principles and challenges. Soft Matter 7, 11047\u201311053 (2011)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref3\">3<\/a>, <a id=\"ref-link-4\" title=\"Xue, L., Kovalev, A., Eichler-Volf, A., Steinhart, M. &amp; Gorb, S. N. Humidity-enhanced wet adhesion on insect-inspired fibrillar adhesive pads. Nat. Commun. 6, 6621 (2015)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref4\">4<\/a>, <a id=\"ref-link-5\" title=\"Chen, Y., Shih, M.-C., Wu, M.-H., Yang, E.-C. &amp; Chi, K.-J. Underwater attachment using hairs: the functioning of spatula and sucker setae from male diving beetles. J. R. Soc. Interface 11, 20140273 (2014)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref5\">5<\/a>, <a id=\"ref-link-6\" title=\"Kovalev, A. E., Varenberg, M. &amp; Gorb, S. N. Wet versus dry adhesion of biomimetic mushroom-shaped microstructures. Soft Matter 8, 7560\u20137566 (2012)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref6\">6<\/a><\/sup>, supramolecular structures comprising nanoparticles<sup><a id=\"ref-link-7\" title=\"Rose, S. et al. Nanoparticle solutions as adhesives for gels and biological tissues. Nature 505, 382\u2013385 (2014)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref7\">7<\/a><\/sup>, and chemistry-based attractants that use various protein polyelectrolytes<sup><a id=\"ref-link-8\" title=\"Zhao, Q. et al. Underwater contact adhesion and microarchitecture in polyelectrolyte complexes actuated by solvent exchange. Nat. Mater. 15, 407\u2013412 (2016)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref8\">8<\/a>, <a id=\"ref-link-9\" title=\"Lee, S.-B., Gonz\u00e1lez-Cabezas, C., Kim, K.-M., Kim, K.-N. &amp; Kuroda, K. Catechol-functionalized synthetic polymer as a dental adhesive to contaminated dentin surface for a composite restoration. Biomacromolecules 16, 2265\u20132275 (2015)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref9\">9<\/a>, <a id=\"ref-link-10\" title=\"White, J. D. &amp; Wilker, J. J. Underwater bonding with charged polymer mimics of marine mussel adhesive proteins. Macromolecules 44, 5085\u20135088 (2011)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref10\">10<\/a><\/sup>. However, it is challenging to develop adhesives that are simple to make and also perform well\u2014and repeatedly\u2014under both wet and dry conditions, while avoiding non-chemical contamination on the adhered surfaces<sup><a id=\"ref-link-11\" title=\"Kim, D.-H. et al. Epidermal electronics. Science 333, 838\u2013843 (2011)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref11\">11<\/a><\/sup>. Here we present an artificial, biologically inspired, reversible wet\/dry adhesion system that is based on the dome-like protuberances found in the suction cups of octopi. To mimic the architecture of these protuberances<sup><a id=\"ref-link-12\" title=\"Tramacere, F. et al. The morphology and adhesion mechanism of Octopus vulgaris suckers. PLoS One 8, e65074 (2013)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref12\">12<\/a>, <a id=\"ref-link-13\" title=\"Tramacere, F., Kovalev, A., Kleinteich, T., Gorb, S. N. &amp; Mazzolai, B. Structure and mechanical properties of Octopus vulgaris suckers. J. R. Soc. Interface 11, 20130816 (2013)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref13\">13<\/a>, <a id=\"ref-link-14\" title=\"Tramacere, F., Pugno, N. M., Kuba, M. J. &amp; Mazzolai, B. Unveiling the morphology of the acetabulum in octopus suckers and its role in attachment. Interface Focus 5, 20140050 (2014)\" href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html#ref14\">14<\/a><\/sup>, we use a simple, solution-based, air-trap technique that involves fabricating a patterned structure as a polymeric master, and using it to produce a reversed architecture, without any sophisticated chemical syntheses or surface modifications. The micrometre-scale domes in our artificial adhesive enhance the suction stress. This octopus-inspired system exhibits strong, reversible, highly repeatable adhesion to silicon wafers, glass, and rough skin surfaces under various conditions (dry, moist, under water and under oil). To demonstrate a potential application, we also used our adhesive to transport a large silicon wafer in air and under water without any resulting surface contamination.<\/p>\n<p><strong>Fuente:<\/strong> <em><a href=\"http:\/\/www.nature.com\/nature\/journal\/v546\/n7658\/full\/nature22382.html\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/www.nature.com<\/a><\/em><\/p>\n","protected":false},"excerpt":{"rendered":"<p>La ciencia siempre ha tratado de usar los ejemplos de la naturaleza para inspirarse en la soluci\u00f3n de retos tecnol\u00f3gicos, como poner a la gente&hellip; <\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[29,24],"tags":[],"_links":{"self":[{"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/posts\/2069"}],"collection":[{"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=2069"}],"version-history":[{"count":0,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/posts\/2069\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=2069"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=2069"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=2069"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}