{"id":3336,"date":"2018-10-03T14:10:11","date_gmt":"2018-10-03T17:10:11","guid":{"rendered":"https:\/\/www.nachodelatorre.com.ar\/mosconi\/?p=3336"},"modified":"2018-10-03T14:10:11","modified_gmt":"2018-10-03T17:10:11","slug":"desarrollos-recientes-en-materiales-elastomericos-para-su-uso-como-blindaje-termico-en-motores-cohete-y-perspectivas-futuras","status":"publish","type":"post","link":"https:\/\/www.fie.undef.edu.ar\/ceptm\/?p=3336","title":{"rendered":"Desarrollos recientes en materiales elastom\u00e9ricos para su uso como blindaje t\u00e9rmico en motores cohete y perspectivas futuras"},"content":{"rendered":"<p align=\"JUSTIFY\"><span style=\"font-size: medium;\"><span lang=\"es-ES\">La posibilidad de que se produzca una ruptura catastr\u00f3fica durante el vuelo de cohetes y misiles exige una investigaci\u00f3n focalizada en el aislamiento de los motores de cohetes. En la actualidad, la optimizaci\u00f3n de pol\u00edmeros ablativos como aislamiento para el tubo s\u00f3lida del motor cohete tiene un papel determinante en el \u00e9xito de estos. <\/span><\/span><!--more--><\/p>\n<div class=\"abstract-group\">\n<section id=\"section-1-en\" class=\"article-section article-section__abstract\" lang=\"en\" data-lang=\"en\">\n<div class=\"article-section__content en main\">\n<p>Catastrophic breakdown that occurs during the flight of supersonic vehicles demands more focused research in the insulation of rocket engines. At present, optimization of polymeric ablatives as viable insulation for solid rocket motor casing has a prominent role in the successful mission of rockets. Among polymers, elastomer serves an imperative part. Comprehensive investigations were disclosed, especially in the elastomeric heat shielding materials with various reinforcing agents. In this paper, research progress of mostly used elastomers is reviewed, and a circumstantial understanding about the features of ablation and insulation has been validated.<\/p>\n<\/div>\n<\/section>\n<\/div>\n<section class=\"article-section article-section__full\">\n<div id=\"pat4101-sec-0001\" class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0001-title\" class=\"article-section__title section__title section1\">1 INTRODUCTION<\/h2>\n<p>Space industry plays an important role in a country&#8217;s economic and national level prestige in the military and civilian purposes or the designing of forthcoming proposals to launch space craft into outer space. Progress in the science and technology made enormous contributions that illuminated the successful transportation of material things surpassing the earth&#8217;s atmosphere. Rockets deliver payloads for scrutinizing the assigned defensive or investigative space missions. Every aircraft entering into any planetary surface at hypersonic speeds can cause severe aerodynamic heating (around 2000\u20103000\u00a0K<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0001\" data-tab=\"pane-pcw-references\">1<\/a>) on the outside of the vehicle due to the burning of solid propellant.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0002\" data-tab=\"pane-pcw-references\">2<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0004\" data-tab=\"pane-pcw-references\">4<\/a>\u00a0Therefore, to protect the vehicle from miserable failure of spacecraft, some design features are added to cope with the aerodynamic heating.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0005\" data-tab=\"pane-pcw-references\">5<\/a>Thermal protection system (TPS) materials impart heat shield to protect the structure, aerodynamic surface and the payload of missiles, and those vehicles interacting with the hypersonic environment.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0006\" data-tab=\"pane-pcw-references\">6<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0007\" data-tab=\"pane-pcw-references\">7<\/a><\/p>\n<p>Polymeric ablative materials serve to effect as TPS that defends space vehicles and probes during the atmospheric entry; they are effective to produce passively cooled rocket combustion chambers<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0008\" data-tab=\"pane-pcw-references\">8<\/a>\u00a0and to render insulation to the solid rocket motors (SRMs) at high temperature.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0009\" data-tab=\"pane-pcw-references\">9<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0011\" data-tab=\"pane-pcw-references\">11<\/a>\u00a0Although some nonpolymeric materials such as inorganic polymers\/ceramics or metals have been used as ablative TPS, polymeric ablatives represent the most flexible category of ablatives. In contrast to the inorganic polymers, polymer ablatives have more inborn benefits: high\u2010heat shock resistance, lower density, good mechanical strength, and thermal insulation capabilities.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0012\" data-tab=\"pane-pcw-references\">12<\/a><\/p>\n<p>The broad range of heat shielding materials (HSMs) for rocket motor casing is produced from reinforced thermosets or elastomers.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0013\" data-tab=\"pane-pcw-references\">13<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0019\" data-tab=\"pane-pcw-references\">19<\/a>\u00a0The most assuring material for the HSM for rocket motors is the elastomers, which can be produced as rubbers, foamed rubbers, or fiber\u2010reinforced composite materials. On the grounds of lightweight, low thermal conductivity, stability in the mechanical and thermal stresses during the operation, elastomeric HSMs (EHSMs) can find relevance in the insulation of SRM casing where thermal insulation is a prime necessity. They do not possess the ability to form cokes without the introduction of special additives due to the linear chain structure of elastomers, thus no solid carbonic residue on thermal decomposition. Also, elastomers have high elongation at break and the capacity to withstand the mechanical and the thermal stresses during the manufacturing and in use.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0020\" data-tab=\"pane-pcw-references\">20<\/a><\/p>\n<p>This review puts the elastomeric materials as ablative insulators for SRM into frame and would confer the readers the progress that has been attained in developing relatively low surface eroding and ablative insulating systems for SRM. These systems can be used to manufacture variety of ablative TPS systems for rocket motor casing application and would provide an idea regarding the composite system that would behave elastomeric as well as ablative. Scrutinizing these systems would pursue the researchers to take the advantage of elastomeric materials for rocket motor casing insulation application.<\/p>\n<\/div>\n<div id=\"pat4101-sec-0002\" class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0002-title\" class=\"article-section__title section__title section1\">2 BROADNESS TO SRM INSULATION<\/h2>\n<p>Solid rocket motors are still used today because of its simplicity and reliable launching features.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0021\" data-tab=\"pane-pcw-references\">21<\/a>\u00a0Among the 2 types of basic systems, cartridge\u2010loaded systems are used for defense applications and the case\u2010bonded ones for the longer range and higher payload service capacity.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0022\" data-tab=\"pane-pcw-references\">22<\/a>\u00a0Solid rocket motor consists of an outer casing with the purpose to accommodate the propellant grains. Solid rocket motor case is usually fabricated from metals such as steel or carbon\/epoxy filament wound composite.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0008\" data-tab=\"pane-pcw-references\">8<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0010\" data-tab=\"pane-pcw-references\">10<\/a>\u00a0Figure\u00a0<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-fig-0001\">1<\/a>\u00a0represents the component parts of an SRM. To be a good casing component, it needs to satisfy various requisites both thermally and mechanically.<\/p>\n<ul class=\"unordered-list\">\n<li>It must have outstanding bonding with the propellant and outer motor covering throughout the whole working temperature range of rocket motor.<\/li>\n<li>Low ablation rate (0.09 to 0.2\u00a0mm\/s) and low density to lower the dormant mass of the thrust unit.<\/li>\n<li>Low thermal conductivity in the range of 4 to 5\u00a0\u00d7\u00a010<sup>\u22124<\/sup>\u00a0Cal\/cm\/\u00b0C and high specific heat in the range of 0.4 to 0.5\u00a0Cal\/g\/\u00b0C.<\/li>\n<li>Formation of porous char with smaller dimensional change and good adhesion.<\/li>\n<li>Able to tolerate mechanical and thermal stress during the operation and handling of the components.<\/li>\n<li>Low moisture absorption with good aging behavior (minimum of 10\u00a0y of shelf life).<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0024\" data-tab=\"pane-pcw-references\">24<\/a><\/li>\n<li>Minimize the specific gravity to &lt;1.15\u00a0g\/cm<sup>3<\/sup>\u00a0for increasing its firing range.<\/li>\n<\/ul>\n<section class=\"article-section__inline-figure\">\n<figure id=\"pat4101-fig-0001\" class=\"figure\"><source srcset=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/22e157c4-bd64-4f16-a971-b31882256e87\/pat4101-fig-0001-m.jpg\" media=\"(min-width: 1650px)\" \/><a href=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/22e157c4-bd64-4f16-a971-b31882256e87\/pat4101-fig-0001-m.jpg\" target=\"_blank\" rel=\"noopener noreferrer\"><img class=\"figure__image\" src=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/21bd2ce5-e650-40a5-a688-693167a9292f\/pat4101-fig-0001-m.png\" alt=\"\" data-lg-src=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/22e157c4-bd64-4f16-a971-b31882256e87\/pat4101-fig-0001-m.jpg\" \/><\/a><figcaption class=\"figure__caption\">\n<div class=\"figure__caption__header\"><strong class=\"figure-title\">Figure 1<\/strong><\/div>\n<\/figcaption><\/figure>\n<\/section>\n<\/div>\n<\/section>\n<div class=\"figure-extra\"><a class=\"open-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#\">Open in figure viewer<\/a><a class=\"ppt-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/action\/downloadFigures?id=pat4101-fig-0001&amp;doi=10.1002%2Fpat.4101\">PowerPoint<\/a><\/div>\n<div>Solid rocket motor component parts<span class=\"figureLink bibLink tab-link\"><a class=\"figureLink bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0023\" data-tab=\"pane-pcw-references\">23<\/a><\/span>\u00a0[Colour figure can be viewed at\u00a0<a class=\"linkBehavior\" href=\"http:\/\/wileyonlinelibrary.com\/\">wileyonlinelibrary.com<\/a>]<\/div>\n<p>The casing\u2010enclosed propellant is systematized to endure combustion, and as a result of that, it achieves the needed thrust for acquiring the rocket propulsion.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0025\" data-tab=\"pane-pcw-references\">25<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0026\" data-tab=\"pane-pcw-references\">26<\/a>\u00a0Thermal environment in the combustion chamber will be above 3000\u00a0K, and the radiation process attained by the combustion products may affect the structural integrity of the SRM. Consequently, internal ablative insulation is provided for shielding the rocket motor from the combustion of propellant grains.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0027\" data-tab=\"pane-pcw-references\">27<\/a>\u00a0A seam of heat barrier material positioned between the internal surfaces of the outer protective covering of an SRM and the propellant can be marked out to be the internal insulation for the solid rocket casing.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0028\" data-tab=\"pane-pcw-references\">28<\/a>\u00a0The cardinal task of internal insulation is to avoid the rocket motor casing from reaching high temperatures that may risk the structural virtue of the outer casing<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0028\" data-tab=\"pane-pcw-references\">28<\/a>\u00a0(Figure\u00a0<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-fig-0002\">2<\/a>\u00a0represents the cross\u2010sectional view of SRM outer casing). Also, interior insulation of the rocket motor casing also performs several auxiliary roles: (1) It hinders the burning on the propellant piece surfaces, where the combustion is objectionable; (2) it acts as a shock\u2010absorbing piston during the conveyance of case stretch into the propellant; (3) it controls the transfer of chemical species within the motor; (4) the impact of combustion products over the case can be obstructed; and (5) it encloses the case, joints, and fittings to avoid the fall in pressure and ruin from the hot burnt ones and (6) for pointing of the burnt products into the nozzle with the maximum limit that could be attainable.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0029\" data-tab=\"pane-pcw-references\">29<\/a><\/p>\n<section class=\"article-section__inline-figure\">\n<figure id=\"pat4101-fig-0002\" class=\"figure\"><source srcset=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/2456dec8-f355-41f0-adf8-a0b624c8b561\/pat4101-fig-0002-m.jpg\" media=\"(min-width: 1650px)\" \/><a href=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/2456dec8-f355-41f0-adf8-a0b624c8b561\/pat4101-fig-0002-m.jpg\" target=\"_blank\" rel=\"noopener noreferrer\"><img class=\"figure__image\" src=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/c94d6ea1-808c-4278-87a8-36275ade724f\/pat4101-fig-0002-m.png\" alt=\"\" data-lg-src=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/2456dec8-f355-41f0-adf8-a0b624c8b561\/pat4101-fig-0002-m.jpg\" \/><\/a><figcaption class=\"figure__caption\">\n<div class=\"figure__caption__header\"><strong class=\"figure-title\">Figure 2<\/strong><\/p>\n<div class=\"figure-extra\"><a class=\"open-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#\">Open in figure viewer<\/a><a class=\"ppt-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/action\/downloadFigures?id=pat4101-fig-0002&amp;doi=10.1002%2Fpat.4101\">PowerPoint<\/a><\/div>\n<\/div>\n<div>Cross\u2010sectional view of a solid rocket motor outer casing [Colour figure can be viewed at\u00a0<a class=\"linkBehavior\" href=\"http:\/\/wileyonlinelibrary.com\/\">wileyonlinelibrary.com<\/a>]<\/div>\n<\/figcaption><\/figure>\n<\/section>\n<div id=\"pat4101-sec-0003\" class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0003-title\" class=\"article-section__title section__title section1\">3 ABLATIVE INSULATION: A NECESSITY<\/h2>\n<p>Ablative materials are outlined for anticipating the thermal protection to the systemic parts exposed in drastic thermal environments.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0008\" data-tab=\"pane-pcw-references\">8<\/a>\u00a0Therefore, those materials can have a significant arena in aerospace technology. Along with the exterior parts of missiles and rockets, they have a prominent role in the insulation of SRM. Ablatives are capable to consume high heat, good heat allocation, better insulation, lightweight, good resilience, easy to find, cheap, and can be easily designed for a particular purpose.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0024\" data-tab=\"pane-pcw-references\">24<\/a>\u00a0These materials are superior insulators, because comparatively low amount of heat gets transferred to the rocket motor structure when ablatives are manipulated as insulators. Therefore, focusing on the ablative composites for HSM in SRM can be a most effective choice of insulating materials.<\/p>\n<p>High temperature\u2013resistant metals or alloys that are used in the rocket motor components alone cannot outlast during the working conditions of the motor. Metal component parts are necessary to provide skeleton of a rocket motor. Along with that, ablative materials are essential for thermal safeguard of the rocket motor. Due to its low thermal conductivity, specialized burning and natural evolution of vigorous char on the exterior of insulator by the automated heat and mass transference.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0030\" data-tab=\"pane-pcw-references\">30<\/a>\u00a0Thermal derogation of ablatives and the decadence of the culminated volatiles consume most of the pyrolysis heat.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0031\" data-tab=\"pane-pcw-references\">31<\/a><\/p>\n<p>Ablation reaction triggers by the virgin material pyrolysis. It can be observed in Figure\u00a0<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-fig-0003\">3<\/a>\u00a0that as the pyrolysis reaction advances, volume of virgin material lowers and char volume increases. Selection of proper ablative material relies on the hyperthermal environment (temperature, pressure, shear rate, and conditions of the atmosphere) in which the TPS is needed to function.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0009\" data-tab=\"pane-pcw-references\">9<\/a>\u00a0There is no single material that satisfies all the operational conditions in a successful manner. Therefore, depending upon the prerequisites, many polymeric ablatives have been developed during the last 5\u00a0decades.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0033\" data-tab=\"pane-pcw-references\">33<\/a>\u00a0Various physicomechancial properties that control the ablative performance in a composite system were represented in Table\u00a0<a class=\"tableLink scrollableLink\" title=\"Link to table\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-tbl-0001\">1<\/a>. Solid residue remained after pyrolysis, gaseous by\u2010products, elemental composition, heat conductivity and heat capacity, permeability of char, and duration of time lasting in the surface of the specimen can be the significant parameters, holding the ablation behavior of a composite.<\/p>\n<section class=\"article-section__inline-figure\">\n<figure id=\"pat4101-fig-0003\" class=\"figure\"><source srcset=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/877ef990-58e0-448d-a54d-323be09fbb35\/pat4101-fig-0003-m.jpg\" media=\"(min-width: 1650px)\" \/><a href=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/877ef990-58e0-448d-a54d-323be09fbb35\/pat4101-fig-0003-m.jpg\" target=\"_blank\" rel=\"noopener noreferrer\"><img class=\"figure__image\" src=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/f9570ea8-a572-4fff-8a96-5fc2e9f43994\/pat4101-fig-0003-m.png\" alt=\"\" data-lg-src=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/877ef990-58e0-448d-a54d-323be09fbb35\/pat4101-fig-0003-m.jpg\" \/><\/a><figcaption class=\"figure__caption\">\n<div class=\"figure__caption__header\"><strong class=\"figure-title\">Figure 3<\/strong><\/p>\n<div class=\"figure-extra\"><a class=\"open-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#\">Open in figure viewer<\/a><a class=\"ppt-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/action\/downloadFigures?id=pat4101-fig-0003&amp;doi=10.1002%2Fpat.4101\">PowerPoint<\/a><\/div>\n<\/div>\n<div>Schematic representation of the ablation process<span class=\"figureLink bibLink tab-link\"><a class=\"figureLink bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0032\" data-tab=\"pane-pcw-references\">32<\/a><\/span>\u00a0[Colour figure can be viewed at\u00a0<a class=\"linkBehavior\" href=\"http:\/\/wileyonlinelibrary.com\/\">wileyonlinelibrary.com<\/a>]<\/div>\n<\/figcaption><\/figure>\n<\/section>\n<div id=\"pat4101-tbl-0001\" class=\"article-table-content\">\n<header class=\"article-table-caption\"><span class=\"table-caption__label\">Table 1.\u00a0<\/span>Component properties in a composite controlling the ablative behavior<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0034\" data-tab=\"pane-pcw-references\">34<\/a><\/header>\n<div class=\"article-table-content-wrapper\">\n<table class=\"table article-section__table\">\n<thead>\n<tr>\n<th class=\"bottom-bordered-cell right-bordered-cell center-aligned\">Components<\/th>\n<th class=\"bottom-bordered-cell center-aligned\">Properties<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">Polymer<\/td>\n<td class=\"left-aligned\">1. Elemental composition2. Molecular mass<\/p>\n<p>3. Degree of cross\u2010linking<\/p>\n<p>4. Tg<\/p>\n<p>5. Thermal decomposition temperature<\/p>\n<p>6. Thermophysical and thermodynamic properties<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">Catalyst or curing agent<\/td>\n<td class=\"left-aligned\">1. Elemental composition2. Percentage retained in polymer<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">Reinforcing agent and fillers<\/td>\n<td class=\"left-aligned\">1. Elemental configuration2. Materialistic nature<\/p>\n<p>3. Alignment in composite<\/p>\n<p>4. Thermal decomposition temperature<\/p>\n<p>5. Thermophysical and thermodynamic properties<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">Ablative materials<\/td>\n<td class=\"left-aligned\">1. Solid residue2. Gaseous products<\/p>\n<p>3. Elemental composition<\/p>\n<p>4. Mechanical properties<\/p>\n<p>5. Permeability and distribution of pores<\/p>\n<p>6. Heat conductivity and specific heat capacity<\/p>\n<p>7. Duration in residue<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">Composite<\/td>\n<td class=\"left-aligned\">1. Uniformity of material distribution2. Presence of defects, voids, etc<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n<p>Polymeric materials can be used over a wide range of hyperthermal conditions,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0035\" data-tab=\"pane-pcw-references\">35<\/a>\u00a0and as long as the pyrolysis starts, these materials get easily removed from the surface of derogation, following the thermal degradation of the insulation layer of SRM.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0009\" data-tab=\"pane-pcw-references\">9<\/a>\u00a0Accordingly, numerous kinds of polymeric ablatives are conventionally used for SRM insulation.<\/p>\n<\/div>\n<div id=\"pat4101-sec-0004\" class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0004-title\" class=\"article-section__title section__title section1\">4 POLYMERIC MATERIALS AS ABLATIVES IN THERMAL PROTECTION: AN OVERVIEW<\/h2>\n<p>In contrast to metals and ceramics that were used in the earlier days of rocket motor insulation, polymeric materials have amassed inherent advantages. Metals mislay their potency at high temperature. Although ceramics excel metals and polymers in their melting temperature, strength, and thermal expansion properties, their brittleness limits their use as structural materials. Advancements in the field of polymers along with the materialization of strong and stiff reinforcements like carbon, silica, and aramid fibers assist to meet the requirements of modern aircraft.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0023\" data-tab=\"pane-pcw-references\">23<\/a><\/p>\n<p>Since polymers can be tuned to different high\u2010temperature environments, polymeric ablatives demonstrate the most adaptable class of HSMs. Different types of polymeric ablatives can be summarized in Figure\u00a0<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-fig-0004\">4<\/a>. They can be fiber\u2010reinforced polymeric ablatives, rigid HSM and EHSM, lightweight ceramic ablators, and nanostructured polymeric ablatives. Ablators with greater charring effects are the predominant ones for thermal insulation in spacecrafts. Over the last 40\u00a0years, high char holding phenolic resins have been used in the production of numerous fiber\u2010stiffened polymeric ablatives.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0036\" data-tab=\"pane-pcw-references\">36<\/a>\u00a0But silica\/phenolic composites acquired with antioxidizing features are the most prevailing ablators.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0008\" data-tab=\"pane-pcw-references\">8<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0030\" data-tab=\"pane-pcw-references\">30<\/a><\/p>\n<section class=\"article-section__inline-figure\">\n<figure id=\"pat4101-fig-0004\" class=\"figure\"><source srcset=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/3755e26d-0c18-4fc2-a5e3-0f98ce4d07d0\/pat4101-fig-0004-m.jpg\" media=\"(min-width: 1650px)\" \/><a href=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/3755e26d-0c18-4fc2-a5e3-0f98ce4d07d0\/pat4101-fig-0004-m.jpg\" target=\"_blank\" rel=\"noopener noreferrer\"><img class=\"figure__image\" src=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/125996f2-107f-4b04-b563-56c22e394d76\/pat4101-fig-0004-m.png\" alt=\"\" data-lg-src=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/3755e26d-0c18-4fc2-a5e3-0f98ce4d07d0\/pat4101-fig-0004-m.jpg\" \/><\/a><figcaption class=\"figure__caption\">\n<div class=\"figure__caption__header\"><strong class=\"figure-title\">Figure 4<\/strong><\/p>\n<div class=\"figure-extra\"><a class=\"open-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#\">Open in figure viewer<\/a><a class=\"ppt-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/action\/downloadFigures?id=pat4101-fig-0004&amp;doi=10.1002%2Fpat.4101\">PowerPoint<\/a><\/div>\n<\/div>\n<div>Classification of polymeric ablatives<span class=\"figureLink bibLink tab-link\"><a class=\"figureLink bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0012\" data-tab=\"pane-pcw-references\">12<\/a><\/span>\u00a0[Colour figure can be viewed at\u00a0<a class=\"linkBehavior\" href=\"http:\/\/wileyonlinelibrary.com\/\">wileyonlinelibrary.com<\/a>]<\/div>\n<\/figcaption><\/figure>\n<\/section>\n<p>Thorough\u2010going exploration in polymeric ablatives initiated at the time of rivalry between the Union of Soviet Socialist Republics and the United States during the 1950s. MX\u20104926 (a composite of carbon fiber of woven rayon and carbon black filler in phenolic matrix) developed by the Cytec Engineered Materials is the most famed material for the standardization of the National Aeronautics and Space Administration and other research federations.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0037\" data-tab=\"pane-pcw-references\">37<\/a>\u00a0Patton et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0038\" data-tab=\"pane-pcw-references\">38<\/a>\u00a0relied upon the MX\u20104926, which is also a phenolic\u2010based composite for the fabrication of polymeric ablatives for their study with inexpensive and readily available vapor\u2010grown carbon fibers. High charring phenolic resin probably be the most vulnerable polymeric material of all the time. Si et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0034\" data-tab=\"pane-pcw-references\">34<\/a>\u00a0prepared phenolic resin incorporated graphene oxide, bestowed with excellent thermal resistance attributed by the good interfacial interaction arising between graphene oxide and phenolic resin inducing the formation of high char environment. Bahramian<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0039\" data-tab=\"pane-pcw-references\">39<\/a>\u00a0incorporated graphite into phenolic matrix, thereby enhancing the thermal properties of the composite with the additional graphite layer formed on the surface of the nanocomposite.<\/p>\n<p>Tate et al,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0037\" data-tab=\"pane-pcw-references\">37<\/a>\u00a0Mirzapour et al,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0040\" data-tab=\"pane-pcw-references\">40<\/a>\u00a0Srebrenkoska,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0041\" data-tab=\"pane-pcw-references\">41<\/a>\u00a0and Srikanth et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0042\" data-tab=\"pane-pcw-references\">42<\/a>\u00a0prepared and evaluated the carbon\u2010phenolic composite, and Bahramian et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0032\" data-tab=\"pane-pcw-references\">32<\/a>\u00a0improvise it again with the addition of graphite and kaolinite. Pulci et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0043\" data-tab=\"pane-pcw-references\">43<\/a>\u00a0demonstrated the effective manufacturing of carbon\u2010phenolic composite for reentry space vehicles. Ding et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0044\" data-tab=\"pane-pcw-references\">44<\/a>\u00a0improved the carbon\u2010phenolic composite with the introduction of zirconium silicide particles. Chen et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0045\" data-tab=\"pane-pcw-references\">45<\/a>improved the ablation performance with the use of zirconium diboride particles in carbon\u2010phenolic matrix. Park et al,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0046\" data-tab=\"pane-pcw-references\">46<\/a>\u00a0Srikanth et al,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0047\" data-tab=\"pane-pcw-references\">47<\/a>\u00a0and Yum et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0048\" data-tab=\"pane-pcw-references\">48<\/a>\u00a0prepared the carbon\u2010phenolic composite with the implementation of carbon nanotube (CNT), whereas Natali et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0049\" data-tab=\"pane-pcw-references\">49<\/a>\u00a0compare the ablative properties of carbon black\u2013reinforced phenolic composites with MWNT\/phenolic composites. While Robert et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0050\" data-tab=\"pane-pcw-references\">50<\/a>\u00a0investigated about the silica\u2010phenolic composite mutated with nanoclay, Paydayesh et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0051\" data-tab=\"pane-pcw-references\">51<\/a>\u00a0evaluated about the organoclay\u2010modified phenolic resin matrix. Wang et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0052\" data-tab=\"pane-pcw-references\">52<\/a>\u00a0and Winya et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0053\" data-tab=\"pane-pcw-references\">53<\/a>\u00a0focused on the incorporation of phenolic resin with nano\u2010aluminum oxide and glass fiber. All those composites that were prepared according to the aforementioned inclusion of different fillers and reinforcements are being exploited in the rocket motor insulation.<\/p>\n<p>As a high\u2010performance resin, epoxy has a popular trademark in the development of polymeric ablatives for insulator rocket motor casing. Yu et al,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0054\" data-tab=\"pane-pcw-references\">54<\/a>\u00a0Ahmad et al,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0055\" data-tab=\"pane-pcw-references\">55<\/a>\u00a0and Puglia et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0056\" data-tab=\"pane-pcw-references\">56<\/a>\u00a0furnished epoxy\u2010based composites and reported about their thermal conductivities. Similarly, Firouzmanesh et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0057\" data-tab=\"pane-pcw-references\">57<\/a>\u00a0prepared carbon\/epoxy novolac composite as leading candidates in SRM insulation with high thermal resistivity and good ablation properties, using the high char retention nature of phenolic resin along with the superlative nature of epoxy. Such type of systems was initially remarked by G. J. Fleming.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0058\" data-tab=\"pane-pcw-references\">58<\/a>\u00a0Even though, polymeric materials are presently handled as insulating materials for SRM, researches are buttoned up to target on the efforts to replace polymers with elastomeric ablative chemical compositions for insulating rocket motor casing applications. The capability of elastomers to get adapted to the deformations under the impact of mechanical\u2010thermal stresses can be the reason for relying on elastomers as HSM for rocket motors.<\/p>\n<\/div>\n<div id=\"pat4101-sec-0005\" class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0005-title\" class=\"article-section__title section__title section1\">5 ABLATION IN ELASTOMERS<\/h2>\n<p>Ablation process empowers the structural materials to sustain and bestow safety in harsh environments. It can be defined as a well\u2010organized heat and mass transfer action where large quantity of heat energy gets scattered during a short period with typical loss of material. It is a complicated procedure encompassing phase changes like melting vaporization, sublimation, and pyrolysis.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0059\" data-tab=\"pane-pcw-references\">59<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0060\" data-tab=\"pane-pcw-references\">60<\/a>\u00a0Ablative composites follow a complex mechanism for providing the thermal safeguard that incorporates heat rejection through reradiation, action of heat generated from the deterioration of the materials, insulation, enormous heat absorption, and the latent heat of thermal deterioration. Ablating elastomeric shielding uses up the heat generated from the propellant pyrolysis gases with the coalescence of enthalpy of heat changes (heat needed to augment the temperature of pyrolyzed species from atmosphere to temperature of propellant ignition gas).<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0009\" data-tab=\"pane-pcw-references\">9<\/a><\/p>\n<p>When the ablative materials decompose, it yields pyrolysis gases at the reaction site that deteriorate forming a char blanket at higher temperatures. The existence of char layer controls the entry of heat into the surface, and it produces an abrupt temperature gradient.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0061\" data-tab=\"pane-pcw-references\">61<\/a>\u00a0Those pyrolytic species get trapped in the boundary layer; enthalpy gets lowered, undergoing thermochemical reaction. The ablation process can be followed up by a scheme of reactions represented in Figure\u00a0<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-fig-0005\">5<\/a>. The ablated organic species upgrade to a surface char covering, which removes the thermally ambiguous polymer from the extremely huge temperature atmosphere. This surface char layer consumes heat by endothermic processes, provides heat capacity at extreme temperature environment, and adds up secondary endothermic reactions with the liberation of hydrocarbon gases or residual reinforcing agent.<\/p>\n<section class=\"article-section__inline-figure\">\n<figure id=\"pat4101-fig-0005\" class=\"figure\"><source srcset=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/7b4c3b5d-20f8-4df3-9aa6-f09d88432bf8\/pat4101-fig-0005-m.jpg\" media=\"(min-width: 1650px)\" \/><a href=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/7b4c3b5d-20f8-4df3-9aa6-f09d88432bf8\/pat4101-fig-0005-m.jpg\" target=\"_blank\" rel=\"noopener noreferrer\"><img class=\"figure__image\" src=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/7e841107-7d44-483f-b263-a0304caba705\/pat4101-fig-0005-m.png\" alt=\"\" data-lg-src=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/7b4c3b5d-20f8-4df3-9aa6-f09d88432bf8\/pat4101-fig-0005-m.jpg\" \/><\/a><figcaption class=\"figure__caption\">\n<div class=\"figure__caption__header\"><strong class=\"figure-title\">Figure 5<\/strong><\/p>\n<div class=\"figure-extra\"><a class=\"open-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#\">Open in figure viewer<\/a><a class=\"ppt-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/action\/downloadFigures?id=pat4101-fig-0005&amp;doi=10.1002%2Fpat.4101\">PowerPoint<\/a><\/div>\n<\/div>\n<div>Mechanism of ablation process [Colour figure can be viewed at\u00a0<a class=\"linkBehavior\" href=\"http:\/\/wileyonlinelibrary.com\/\">wileyonlinelibrary.com<\/a>]<\/div>\n<\/figcaption><\/figure>\n<\/section>\n<p>High surface ejection with low heating rate at the material surface exposed in extreme temperature can disperse an enormous amount of heat via surface radiant emission. Newly formed char will persist with the substrate for a small interval, and a deteriorated layer gets generated below the char layer, where pyrolysis of virgin material occurs. Gases in the deterioration zone percolate with the pressure that enhance the thermochemical reactions to pyrolytic carbon.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0062\" data-tab=\"pane-pcw-references\">62<\/a><\/p>\n<p>If the casing insulation material is not reinforced, the altogether stress developed in the char layer by the pyrolysis gases and thermal expansion causes deteriorated material to escape away from the surface.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0061\" data-tab=\"pane-pcw-references\">61<\/a>\u00a0During the further progress of heating zone, mechanical erosion of the metallic particles in the propellant along with the hot exhaust gases will take place. When the surface layer erodes, the next layer gets vulnerable, and so on the process continues. Large amount of endothermic heat engrossed by the pyrolysis reaction and the porous char layer formed at the surface offers outstanding conservation to the underlying material.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0063\" data-tab=\"pane-pcw-references\">63<\/a>\u00a0Amidst of different polymeric ablatives seen in Figure\u00a0<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-fig-0004\">4<\/a>, elastomeric ablatives represent the most tractile heat shield. Nowadays, elastomers can be the most assuring HSM for SRM.<\/p>\n<\/div>\n<div id=\"pat4101-sec-0006\" class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0006-title\" class=\"article-section__title section__title section1\">6 A FOCUS ON EHSMS FOR SRM<\/h2>\n<p>An HSM needed to be tolerant to act elastic to the anamorphosis concealed by the mechanical and thermal loadings bared during the fabrication and working of the shielding material.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0008\" data-tab=\"pane-pcw-references\">8<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0010\" data-tab=\"pane-pcw-references\">10<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0064\" data-tab=\"pane-pcw-references\">64<\/a>\u00a0In any puncture happening to the insulation material during the operation of SRM, the casing will be susceptible to melting or degradation, and it leads to the permanent failure of rocket motor. Consequently, EHSMs are accounted to insulate the inner surface of rocket engines. It can withstand the temperature up to 2800\u00b0C and pressure 100\u00a0bar (inside the rocket motor).<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0010\" data-tab=\"pane-pcw-references\">10<\/a>\u00a0There are a lot of important requirements that need to satisfy along with the basic necessities for the preparation of an EHSM, making the formulation task of elastomeric insulation more complicated.<\/p>\n<p>Most elastomers can achieve better thermal stability, mechanical strength, improved insulation, better charring process, and ablation insulation performance with the inclusion of chopped fibers or fibrous materials into it.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0065\" data-tab=\"pane-pcw-references\">65<\/a>\u00a0Donskoy suggested that assimilated fillers and the nature of vulcanizing system will alter the competency of HSM.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0066\" data-tab=\"pane-pcw-references\">66<\/a>\u00a0Some elastomers such as ethylene propylene diene monomer (EPDM) and dimethyl silicone rubber have least specific gravity, which break down endothermically and form a char covering in the course of ablation; however, uncompounded elastomers have poor resistance to surface erosion and processing properties. Hence, elastomers are coupled with additives and inorganic fillers for incorporating specific processing attributes, principally to boost the ablation resistance.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0009\" data-tab=\"pane-pcw-references\">9<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0067\" data-tab=\"pane-pcw-references\">67<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0068\" data-tab=\"pane-pcw-references\">68<\/a>\u00a0Elastomeric materials such as nitrile rubber,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0069\" data-tab=\"pane-pcw-references\">69<\/a>\u00a0silicone rubber,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0070\" data-tab=\"pane-pcw-references\">70<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0075\" data-tab=\"pane-pcw-references\">75<\/a>thermoplastic polyurethane (TPU),<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0063\" data-tab=\"pane-pcw-references\">63<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0076\" data-tab=\"pane-pcw-references\">76<\/a>\u00a0and ethylene propylene diene rubber<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0077\" data-tab=\"pane-pcw-references\">77<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0086\" data-tab=\"pane-pcw-references\">86<\/a>\u00a0are mostly used for making an insulation casing for rocket motor cases.<\/p>\n<div id=\"pat4101-sec-0007\" class=\"article-section__sub-content\">\n<h3 class=\"article-section__sub-title section2\">6.1 Nitrile rubber\u2013based HSMs<\/h3>\n<p>Nitrile rubber (Perbunan, Buna\u2010N), a synthetic copolymer of acrylonitrile and butadiene,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0087\" data-tab=\"pane-pcw-references\">87<\/a>\u00a0is used in the development of HSM for rocket motor casing.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0008\" data-tab=\"pane-pcw-references\">8<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0020\" data-tab=\"pane-pcw-references\">20<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0066\" data-tab=\"pane-pcw-references\">66<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0088\" data-tab=\"pane-pcw-references\">88<\/a>\u00a0Heat shielding materials based on nitrile rubber are on vogue in Indian space program.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0089\" data-tab=\"pane-pcw-references\">89<\/a>\u00a0The physical and chemical properties of nitrile rubber depend upon the composition of nitrile content, and it can be resistant to oil and fuels. However, it is able to tolerate a range of temperature from \u221240\u00b0C to108\u00b0C<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0090\" data-tab=\"pane-pcw-references\">90<\/a>; processing of nitrile butadiene rubber (NBR) is probably difficult, due to the strong intermolecular interaction. It can be cross\u2010linked by sulfur or peroxides and vulcanized at temperatures around 140 to 190\u00b0C.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0012\" data-tab=\"pane-pcw-references\">12<\/a>\u00a0Nevertheless counteracted with the limited shelf life, high density (1\u20101.3\u00a0g\/cm<sup>3<\/sup>), and low\u2010temperature properties, NBR is still used as an insulation liner for SRM.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0064\" data-tab=\"pane-pcw-references\">64<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0091\" data-tab=\"pane-pcw-references\">91<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0095\" data-tab=\"pane-pcw-references\">95<\/a>\u00a0Heat shielding material made of NBR usually contains SiO<sub>2<\/sub>\u00a0as a powder and asbestos fibers<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0093\" data-tab=\"pane-pcw-references\">93<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0095\" data-tab=\"pane-pcw-references\">95<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0096\" data-tab=\"pane-pcw-references\">96<\/a>\u00a0for reinforcement and thereby to improve the thermal stability. The aim of NBR use as EHSMs is because of their greater affinity with higher char yield resins such as phenolics, which are added for the betterment of ablation resistance.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0097\" data-tab=\"pane-pcw-references\">97<\/a><\/p>\n<p>A notable archetype of NBR\u2010based HSM was Hitca 6520,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0066\" data-tab=\"pane-pcw-references\">66<\/a>\u00a0used to shield steel case of Titan III\u2010C SRM.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0064\" data-tab=\"pane-pcw-references\">64<\/a>\u00a0Heat shielding material developed by Rock Island Arsenal Company was composed of phenolic resin and asbestos fibers.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0098\" data-tab=\"pane-pcw-references\">98<\/a>\u00a0The elasticity of the modified composite was lost after the incorporation of phenolic resin.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0064\" data-tab=\"pane-pcw-references\">64<\/a>\u00a0GTR\u2010V\u201044, GTR\u2010V\u201045, and Garlock 7765 are some commercially available HSMs made of NBRs with the inclusion of silicon dioxide and asbestos as fillers.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0020\" data-tab=\"pane-pcw-references\">20<\/a>\u00a0Zhao et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0065\" data-tab=\"pane-pcw-references\">65<\/a>\u00a0prepared the chopped polyimide (PI) fiber\u2013filled NBR insulation for SRM by the surface modification of chopped PI fibers under oxygen plasma and thereafter by mixing it with NBR in a 2\u2010roll mill. It showed that the excellent mechanical and ablative properties of the NBR contribute to the high thermal stability of the SRM. Ablation rate decreases with the increase of PI fiber content. Plasma treatment can efficiently enhance the roughness of PI fibers and can form many polar groups on the surfaces, which improvise the interfacial interactions between PI fibers and the NBR matrix. In comparison to the Kevlar\u2010filled NBR, chopped PI\u2010filled NBR shows better insulation. By this method, Zhao et al conclude that this current approach provides better charring and ablative properties as a HSM.<\/p>\n<p>Iqbal<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0097\" data-tab=\"pane-pcw-references\">97<\/a>\u00a0group prepared a composite of NBR with different concentrations of phenol formaldehyde using internal dispersion kneader and 2\u2010roll mixing mill. It was observed that ablation resistance of the composite becomes great and the thermal conduction, shore A hardness, tensile strength got increased with increasing the phenol formaldehyde in the rubber matrix. Guan et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0067\" data-tab=\"pane-pcw-references\">67<\/a>\u00a0conducted a study about the ablative properties of the hydrogenated nitrile rubber using fillers such as organically modified montmorillonite and expanded graphite, compromising many polar nitrile groups and reported that rise in ablation rate and a decline in the linear ablation rate of MMT\u2010reinforced HNBR composite compared to silica or expanded graphite.<\/p>\n<\/div>\n<div id=\"pat4101-sec-0008\" class=\"article-section__sub-content\">\n<h3 class=\"article-section__sub-title section2\">6.2 EPDM\u2010based HSMs<\/h3>\n<p>Generally, insulation used in SRM is composed of organic rubber such as an aramid fiber\u2013filled EPDM.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0099\" data-tab=\"pane-pcw-references\">99<\/a>\u00a0Ethylene propylene diene monomer rubber is a terpolymer of ethylene, propylene, and a diene component (M includes the rubbers having a saturated main chain of methylene group). Figure\u00a0<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-fig-0006\">6<\/a>\u00a0indicates the chemical structure of EPDM elastomer. Commonly used dienes for EPDM are dicyclopentadiene, ethylidenenorbornene, and vinyl norbornene.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0067\" data-tab=\"pane-pcw-references\">67<\/a>\u00a0According to the necessary application of the EPDM, ethylene, propylene, and diene ratio can be varied.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0100\" data-tab=\"pane-pcw-references\">100<\/a>\u00a0Ethylene propylene diene monomer elastomers have been fabricated by using vanadium\u2010based Zeigler\u2010Natta catalyst systems.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0101\" data-tab=\"pane-pcw-references\">101<\/a>\u00a0The reliable mechanical properties like tear strength, immense thermal resistance, and good retention of properties after aging due to the saturated main chain make EPDM rubber as good insulators. Since EPDM is a material with minimal specific gravity, its novel application is in the case\u2010bonded insulation for rocket motors.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0102\" data-tab=\"pane-pcw-references\">102<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0103\" data-tab=\"pane-pcw-references\">103<\/a>\u00a0Also, it has been proven to show better aging properties,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0081\" data-tab=\"pane-pcw-references\">81<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0104\" data-tab=\"pane-pcw-references\">104<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0108\" data-tab=\"pane-pcw-references\">108<\/a>\u00a0and it possess high filler loading capacity.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0104\" data-tab=\"pane-pcw-references\">104<\/a>\u00a0Thermal stability of EPDM is analogous or greater than NBR.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0109\" data-tab=\"pane-pcw-references\">109<\/a><\/p>\n<section class=\"article-section__inline-figure\">\n<figure id=\"pat4101-fig-0006\" class=\"figure\"><source srcset=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/ba9ee0c4-2c95-4de9-ac20-f35e049739ae\/pat4101-fig-0006-m.jpg\" media=\"(min-width: 1650px)\" \/><a href=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/ba9ee0c4-2c95-4de9-ac20-f35e049739ae\/pat4101-fig-0006-m.jpg\" target=\"_blank\" rel=\"noopener noreferrer\"><img class=\"figure__image\" src=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/328766cf-efa4-4504-a457-6dba94d786ff\/pat4101-fig-0006-m.png\" alt=\"\" data-lg-src=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/ba9ee0c4-2c95-4de9-ac20-f35e049739ae\/pat4101-fig-0006-m.jpg\" \/><\/a><figcaption class=\"figure__caption\">\n<div class=\"figure__caption__header\"><strong class=\"figure-title\">Figure 6<\/strong><\/p>\n<div class=\"figure-extra\"><a class=\"open-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#\">Open in figure viewer<\/a><a class=\"ppt-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/action\/downloadFigures?id=pat4101-fig-0006&amp;doi=10.1002%2Fpat.4101\">PowerPoint<\/a><\/div>\n<\/div>\n<div>Structure of ethylene propylene diene monomer<\/div>\n<\/figcaption><\/figure>\n<\/section>\n<p>Saturated main chain is the reason behind the thermal stability of EPDM.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0110\" data-tab=\"pane-pcw-references\">110<\/a>\u00a0It has reliable low\u2010temperature properties: Tg of \u221250\u00b0C, permitting them to be used in different environmental conditions.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0109\" data-tab=\"pane-pcw-references\">109<\/a>\u00a0It has well\u2010known resistance to oxidation, ozonization, weathering changes, and superior low\u2010temperature properties. It also has the lowest density among the elastomers approximately 0.85\u00a0g\/cm<sup>3<\/sup>.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0111\" data-tab=\"pane-pcw-references\">111<\/a>\u00a0This lower density has a prominent significance in the reduced weight of HSM. Therefore, such kind of elastomers can be used for SRM with high payload capacity.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0022\" data-tab=\"pane-pcw-references\">22<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0066\" data-tab=\"pane-pcw-references\">66<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0084\" data-tab=\"pane-pcw-references\">84<\/a>\u00a0In addition to the above mentioned properties, the weight of the launching vehicle and satellite performs a massive role in rocket flight. Table\u00a0<a class=\"tableLink scrollableLink\" title=\"Link to table\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-tbl-0002\">2<\/a>\u00a0gives the data about the specific gravity of different elastomeric ablators. Therefore, researches are concentrated to find a proper substitute for nitrile rubber (specific gravity of 0.97\u20101.00) with EPDM rubber (specific gravity of 0.80\u20100.87).<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0105\" data-tab=\"pane-pcw-references\">105<\/a><\/p>\n<div id=\"pat4101-tbl-0002\" class=\"article-table-content\">\n<header class=\"article-table-caption\"><span class=\"table-caption__label\">Table 2.\u00a0<\/span>Specific gravity of different elastomeric ablators<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0130\" data-tab=\"pane-pcw-references\">130<\/a><\/header>\n<div class=\"article-table-content-wrapper\">\n<table class=\"table article-section__table\">\n<thead>\n<tr>\n<th class=\"bottom-bordered-cell right-bordered-cell center-aligned\">Different Elastomeric Ablators<\/th>\n<th class=\"bottom-bordered-cell center-aligned\">Specific Gravity<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">Dimethyl RTV, low density system<\/td>\n<td class=\"center-aligned\">0.87<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">Phenyl\u2010methyl RTV<\/td>\n<td class=\"center-aligned\">1.40<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">All methyl elastomers<\/td>\n<td class=\"center-aligned\">1.17<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">All phenyl\u2010methyl elastomers<\/td>\n<td class=\"center-aligned\">1.57<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<\/div>\n<p>Ethylene propylene diene monomer is used as both primary and secondary polymer to enhance the bonding properties; otherwise, it will give lesser bonding characteristics. Addition of high levels of fibrous reinforcement to elastomeric matrix can regulate the mechanical properties of the HSM.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0069\" data-tab=\"pane-pcw-references\">69<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0085\" data-tab=\"pane-pcw-references\">85<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0112\" data-tab=\"pane-pcw-references\">112<\/a>\u00a0Ethylene propylene diene monomer with carbon fiber,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0113\" data-tab=\"pane-pcw-references\">113<\/a>\u00a0aramid fiber,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0111\" data-tab=\"pane-pcw-references\">111<\/a>\u00a0silica, PI,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0081\" data-tab=\"pane-pcw-references\">81<\/a>\u00a0and hydroxyl\u2010terminated polybutadiene<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0114\" data-tab=\"pane-pcw-references\">114<\/a>has been used profitably in rocket motor insulation. Along with that various additives such as fillers, plasticizers, activators, accelerators, curatives, antioxidants, tackifiers, and flame retardants are involved in a typical EPDM insulation formulation.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0084\" data-tab=\"pane-pcw-references\">84<\/a>\u00a0Fillers such as carbon fiber, silica, asbestos, cork, and glass fiber can be used for improving the ablative efficiency.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0115\" data-tab=\"pane-pcw-references\">115<\/a>\u00a0Some of the EPDM composites that are used as insulating material for rocket motor casing are listed in the Table\u00a0<a class=\"tableLink scrollableLink\" title=\"Link to table\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-tbl-0003\">3<\/a>.<\/p>\n<div id=\"pat4101-tbl-0003\" class=\"article-table-content\">\n<header class=\"article-table-caption\"><span class=\"table-caption__label\">Table 3.\u00a0<\/span>Some EPDM formulations existed for rocket motor casing insulator<\/header>\n<div class=\"article-table-content-wrapper\">\n<table class=\"table article-section__table\">\n<thead>\n<tr>\n<th class=\"bottom-bordered-cell right-bordered-cell left-aligned\">Sl no.<\/th>\n<th class=\"bottom-bordered-cell center-aligned\">EPDM Composite Formulation<\/th>\n<th class=\"bottom-bordered-cell center-aligned\">Observation<\/th>\n<th class=\"bottom-bordered-cell center-aligned\">Reference<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">1<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0asbestos fiber\/Fe<sub>2<\/sub>O<sub>3<\/sub>\/cork powder\u00a0+\u00a0curing agents\u00a0+\u00a0additives<\/td>\n<td class=\"left-aligned\">Decrease in mass loss and erosion and an improvement in the heat of ablation due to the increase in fiber loading.<\/td>\n<td class=\"center-aligned\">115<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">2<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0epoxy\u00a0+\u00a0curing agents\u00a0+\u00a0additives<\/td>\n<td class=\"left-aligned\">Resistance to ablation can be better improved with higher melting point substrates and by enhancing the matrix\u2010substrate interaction.<\/td>\n<td class=\"center-aligned\">82<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">3<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0chlorosulfonated polyethylene\u00a0+\u00a0HTPB\u00a0+\u00a0silica powder\u00a0+\u00a0napthenic oil\u00a0+\u00a0sulfur\u2010thiuram<\/td>\n<td class=\"left-aligned\">Incorporation of polar CSE to the rubber matrix will improve the interfacial bonding between insulator and propellant. HTPB facilitates the processing and peel strength of EPDM rubber. Amount of HTPB added influenced the interfacial bonding levels of nonpolar EPDM matrix.<\/td>\n<td class=\"center-aligned\">114<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">4<\/td>\n<td class=\"left-aligned\">Maleated EPDM\u00a0+\u00a0melamine fiber\u00a0+\u00a0resorcinol\u00a0+\u00a0hexa\u00a0+\u00a0precipitated silica\u00a0+\u00a0ZnO\u00a0+\u00a0Zn stearate<\/td>\n<td class=\"left-aligned\">Using the excellent heat insulating and flame resistant nature of melamine formaldehyde, showed improved insulating behavior of the composite<\/td>\n<td class=\"center-aligned\">168<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">5<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0liquid EPDM\u00a0+\u00a0PSA pulp\u00a0+\u00a0nanosilica\u00a0+\u00a0sulfur\u00a0+\u00a0ZnO\u00a0+\u00a0stearic acid\u00a0+\u00a02\u2010sulfonyl dibenzo thiazole\u00a0+\u00a0dipenyl guanidine<\/td>\n<td class=\"left-aligned\">Addition of 10\u00a0phr of pretreated polysulfonamide pulp to EPDM matrix, 3\u2010fold improvements in the ablative properties and a slight decrease in the tensile strength is seen.<\/td>\n<td class=\"center-aligned\">169<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">6<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0carbon black\u00a0+\u00a0DCP\u00a0+\u00a0stearic acid\u00a0+\u00a0ZnO\u00a0+\u00a0antioxidant<\/td>\n<td class=\"left-aligned\">Carbon black, surface area controls the cure kinetics of carbon black\/EPDM composite. Sulfur at the surface of carbon black helps in EPDM composite vulcanization.<\/td>\n<td class=\"center-aligned\">79<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">7<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0liquid EPDM\u00a0+\u00a0nanosilica\u00a0+\u00a0additives\u00a0+\u00a0curing agents\u00a0+\u00a0PSA short fibers\/aramid fiber<\/td>\n<td class=\"left-aligned\">Degradation peak of PSA fiber was 100\u00b0 higher than that of aramid fiber. Increasing the fiber content in both the composite decrease the ablation rate initially and then increases. Ablation rate and thermal conductivity of PSA\/EPDM composite is greater than aramid\/EPDM composite.<\/td>\n<td class=\"center-aligned\">170<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">8<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0aramid pulp\/kynol\/silica short fibers\u00a0+\u00a0nanosilica<\/td>\n<td class=\"left-aligned\">EPDM\/kynol gives out a char with smaller dimensional change and shows good adhesion on the virgin material. Insulation properties of EPDM\/aramid composite are noteworthy. EPDM\/silica showed poor performance.<\/td>\n<td class=\"center-aligned\">111<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">9<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0liquid EPDM\u00a0+\u00a0polysulfonamide pulp\u00a0+\u00a0nanosilica\u00a0+\u00a0epoxy phenolic resin\u00a0+\u00a0additives\u00a0+\u00a0curing agents<\/td>\n<td class=\"left-aligned\">Composite provides a strong char layer after pyrolysis. With 10\u00a0phr of epoxy phenolic resin, a 2\u2010fold increase in the ablative properties of the composite is observed. Also it promotes the interfacial bonding within the composite.<\/td>\n<td class=\"center-aligned\">171<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">10<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0surface modified polyimide\u00a0+\u00a0additives\u00a0+\u00a0DCP\u00a0+\u00a0sulfur<\/td>\n<td class=\"left-aligned\">Surface modified PI gives a rough surface and improves the adhesion between fiber and EPDM matrix. Thereby, showing superlative mechanical and ablative properties.<\/td>\n<td class=\"center-aligned\">168<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">11<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0benzoyl peroxide\u00a0+\u00a0maleic anhydride\u00a0+\u00a0ZnO\u00a0+\u00a0stearic acid\u00a0+\u00a0polyimide\u00a0+\u00a0carbon nanofiber\u00a0+\u00a0antioxidant\u00a0+\u00a0sulfur\u00a0+\u00a0accelerator<\/td>\n<td class=\"left-aligned\">Modification with maleic anhydride improves rubber\u2010filler compatibilization. PI enhances thermal stability and CNF improves mechanical properties and gives off better char yield. Maleic grafted EPDM\/PI\/CNF composite showed good physical and thermo\u2010mechanical properties.<\/td>\n<td class=\"center-aligned\">80<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">12<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0PI\u00a0+\u00a0nanosilica\/nanoclay\/carbon nanofiber\u00a0+\u00a0curatives<\/td>\n<td class=\"left-aligned\">Low density and enhanced mechanical properties acquired by the EPDM\/PI\/nanocomposite. EPDM\/PI\/nanosilica displayed superior retention of properties after aging. Composites of these fillers showed same maximum degradation temperature.<\/td>\n<td class=\"center-aligned\">81<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">13<\/td>\n<td class=\"left-aligned\">EPDM\u00a0+\u00a0silica short fibers\u00a0+\u00a0wollastonite\u00a0+\u00a0nanosilica\u00a0+\u00a0aramid fiber<\/td>\n<td class=\"left-aligned\">Makes only a partial replacement of asbestos fiber. Small size length of macron sized needles of wollastonite limits the adhesion between charred and pristine material. It is economical than aramid fibers.<\/td>\n<td class=\"center-aligned\">86<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div class=\"article-section__table-footnotes\">\n<ul>\n<li id=\"pat4101-note-0001\">Abbreviations: CNT, carbon nanotube; CSE, chlorosulphonated polyethylene; DCP, Dicumyl peroxide; EPDM, ethylene propylene diene monomer; HTPB, hydroxy terminated polybutadiene; PI, polyimide; PSA, polysulfonamide.<\/li>\n<\/ul>\n<\/div>\n<\/div>\n<\/div>\n<div id=\"pat4101-sec-0009\" class=\"article-section__sub-content\">\n<h3 class=\"article-section__sub-title section2\">6.3 Silicon rubber\u2013based HSMs<\/h3>\n<p>Silicon rubbers are linear polysiloxanes, which are distinguished according to the curing mechanism as high\u2010temperature vulcanized and room\u2010temperature vulcanized silicon rubbers.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0116\" data-tab=\"pane-pcw-references\">116<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0117\" data-tab=\"pane-pcw-references\">117<\/a>\u00a0Heat shielding materials based on silicone rubber ablative composites are an appealing material for SRM and ramjet propellant.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0118\" data-tab=\"pane-pcw-references\">118<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0120\" data-tab=\"pane-pcw-references\">120<\/a>\u00a0The exceptional thermal stability of silicon rubbers make it a reliable choice for higher temperature applications.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0070\" data-tab=\"pane-pcw-references\">70<\/a>Lots of silicon rubber ablative composites for TPSs are known so far.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0121\" data-tab=\"pane-pcw-references\">121<\/a>&#8211;<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0123\" data-tab=\"pane-pcw-references\">123<\/a>\u00a0Polydimethyl siloxane, a familiar associative of this family, is stable to 300\u00b0C under vacuum.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0124\" data-tab=\"pane-pcw-references\">124<\/a>\u00a0The siloxane bonds in silicon are highly stable and have high binding energy (106\u00a0kcal\/mol) compared with carbon bonds (84.9\u00a0kcal\/mol), and therefore, silicone rubbers have high thermal stability, chemical resistance, and have better electrical insulation properties than organic rubbers.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0125\" data-tab=\"pane-pcw-references\">125<\/a>\u00a0The addition of methyl phenyl siloxane or diphenyl siloxane as a copolymer with polydimethyl siloxane has been proven to increase the degradation temperature to 400\u00b0C.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0126\" data-tab=\"pane-pcw-references\">126<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0127\" data-tab=\"pane-pcw-references\">127<\/a><\/p>\n<p>Polydimethyl siloxane is the most common silicon elastomer that is used as a matrix for SRM. At higher temperatures, it decomposes with the liberation of volatile compounds such as H<sub>2<\/sub>0, CO<sub>2<\/sub>, and methanol.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0012\" data-tab=\"pane-pcw-references\">12<\/a>\u00a0The carbonaceous char obtained after the pyrolysis contains mainly silicon compounds such as SiO<sub>2<\/sub>\u00a0and SiCO.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0128\" data-tab=\"pane-pcw-references\">128<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0129\" data-tab=\"pane-pcw-references\">129<\/a>\u00a0Silicon elastomers are considered as charring ablators. Depending on the nature of aerodynamic and vibrational forces acting on the charring material, char is either removed or remained on the ablator surface.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0130\" data-tab=\"pane-pcw-references\">130<\/a>Heat shielding materials are prepared by blending silicone rubbers with fillers, fibers, and vulcanizing agents. Flame retardant additives such as antimony trioxide and polychlorinated compounds can be used.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0131\" data-tab=\"pane-pcw-references\">131<\/a>\u00a0They have been practically applied as thermal protection components of Saturn V and Polaris rockets. Baldwin et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0132\" data-tab=\"pane-pcw-references\">132<\/a>\u00a0demonstrated the use of certain siloxane polymers containing a high percentage of vinyl methyl siloxane units as binders for ablative insulation for improving the ablation resistance in high\u2010temperature environment.<\/p>\n<p>Silicon rubber composite comprising silica, SiC, and carbon fibers established by Dow Corning Corporation confronted a test flight successfully.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0133\" data-tab=\"pane-pcw-references\">133<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0134\" data-tab=\"pane-pcw-references\">134<\/a>\u00a0Sanden<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0135\" data-tab=\"pane-pcw-references\">135<\/a>\u00a0developed a higher heat\u2010resistant silicon\u2010based insulating material by mixing silicon rubber materials from Dow Corning and General Electric Company. Kim and his crew<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0136\" data-tab=\"pane-pcw-references\">136<\/a>\u00a0conducted a study about the thermal stability and ablation properties of the silicon rubber composites with clay and carbon fiber and found out that addition of carbon fibers may lower thermal stability of the composite. Torre and his coworkers investigated about the theoretical and experimental attributes of silicon rubber ablative composites.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0019\" data-tab=\"pane-pcw-references\">19<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0137\" data-tab=\"pane-pcw-references\">137<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0138\" data-tab=\"pane-pcw-references\">138<\/a><\/p>\n<p>Yang et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0139\" data-tab=\"pane-pcw-references\">139<\/a>\u00a0prepared an ablative composite of silicone with zirconium carbide (ZrC) or zirconia (ZrO<sub>2<\/sub>), and it is practically certified as TPS. Thermal stabilities, tensile strength, and nature of ablation of the composite increased with the assimilation of ZrC or ZrO<sub>2<\/sub>\u00a0powders. Ablation rate was decreased by 40% and 72% by 40 phr ZrC and ZrO<sub>2<\/sub>, respectively. The ablated surface occupied with ZrO<sub>2<\/sub>, SiO<sub>2<\/sub>, and SiC acted as an effective hurdle for oxygen dispersal and temperature navigation, foiling additional decomposition and erosion, making it as an ablation resistant silicon rubber composite.<\/p>\n<p>Yu et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0140\" data-tab=\"pane-pcw-references\">140<\/a>\u00a0evaluated the thermal constancy and ablation peculiarities of the aluminum silicate ceramic fiber with acicular wollastonite added in a silicon rubber composite and the TGA analysis confirmed that the thermal stability was enhanced by the incorporation of these fillers. A dense ceramic layer formed will act as an effective oxygen and heat barrier, liable for the increase in thermal stability and ablation properties. Liu et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0141\" data-tab=\"pane-pcw-references\">141<\/a>\u00a0investigated about the mechanical, ablation properties of silicon rubber composites incorporated with carbon fibers and observed that the added carbon fibers resist the stretching of rubber matrix. Linear ablation rate was also found to decrease with increasing the carbon fiber content.<\/p>\n<p>Silicon\u2010based insulator, Room Temperature Vulcanized Silicon Rubber, RTV 560, is produced by loading silicon rubber with SiO<sub>2<\/sub>\u00a0and Fe<sub>2<\/sub>O<sub>3<\/sub>\u00a0particles. It decomposes by producing a foamed char containing silica, SiC, and FeSiO<sub>3<\/sub>.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0129\" data-tab=\"pane-pcw-references\">129<\/a>\u00a0DC 93\u2010104,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0142\" data-tab=\"pane-pcw-references\">142<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0143\" data-tab=\"pane-pcw-references\">143<\/a>\u00a0another prominent silicon insulator, is composed of silicone elastomer loaded with silica, silicon carbide, and carbon fibers.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0144\" data-tab=\"pane-pcw-references\">144<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0145\" data-tab=\"pane-pcw-references\">145<\/a>\u00a0It has high viscosity, high char retention, and low ablation rate even under the domination of high shear stress environments<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0020\" data-tab=\"pane-pcw-references\">20<\/a>\u00a0that has been used as protective coating for rocket motor cases<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0120\" data-tab=\"pane-pcw-references\">120<\/a>\u00a0and ramjet combustion chambers.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0099\" data-tab=\"pane-pcw-references\">99<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0146\" data-tab=\"pane-pcw-references\">146<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0147\" data-tab=\"pane-pcw-references\">147<\/a>\u00a0DC 93\u2010104 was modified with asbestos or PI fibers.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0148\" data-tab=\"pane-pcw-references\">148<\/a>\u00a0Stephens et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0149\" data-tab=\"pane-pcw-references\">149<\/a>\u00a0patented for the use of aramid fibers in silicone\u2010based HSM.<\/p>\n<p>Another significant silicone\u2010based TPS material is the super light ablator, eg, Lockheed Martin&#8217;s SLA\u2010561V.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0131\" data-tab=\"pane-pcw-references\">131<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0137\" data-tab=\"pane-pcw-references\">137<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0138\" data-tab=\"pane-pcw-references\">138<\/a>\u00a0It was a low\u2010density material (0.25\u00a0g\/cm<sup>3<\/sup>), initially developed for the Viking Lander missions by Martin Marietta Corporation in 1976.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0131\" data-tab=\"pane-pcw-references\">131<\/a>\u00a0Because of its excellent mass and cost\u2010efficient performance, it has got recertification in the 1990s for Mars Pathfinder Lander (heat flux of 54\u00a0W\/cm<sup>2<\/sup>) and Mars Exploration Rover (115\u00a0W\/cm<sup>2<\/sup>). The ablating performance of HSM, SLA\u2010561V, is verified by testing under shear conditions, and it was applied as a thermal insulator for ramjet combustor.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0150\" data-tab=\"pane-pcw-references\">150<\/a>\u00a0It worked as a charring insulator and showed medium surface erosion in this environment.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0151\" data-tab=\"pane-pcw-references\">151<\/a>\u00a0In 2012, SLA\u2010561V fruitfully protected the Mars Science Laboratory (MSL) capsule during the reentry flight on Mars.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0152\" data-tab=\"pane-pcw-references\">152<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0153\" data-tab=\"pane-pcw-references\">153<\/a>\u00a0Table\u00a0<a class=\"tableLink scrollableLink\" title=\"Link to table\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-tbl-0004\">4<\/a>\u00a0compares the specific gravity of different elastomers, and it is seen that dimethyl RTV silicon rubbers have the least specific gravity, which is well suited for long fire range rocket motor casings.<\/p>\n<div id=\"pat4101-tbl-0004\" class=\"article-table-content\">\n<header class=\"article-table-caption\"><span class=\"table-caption__label\">Table 4.\u00a0<\/span>Ablation rates of different elastomeric HSM composites<\/header>\n<div class=\"article-table-content-wrapper\">\n<table class=\"table article-section__table\">\n<thead>\n<tr>\n<th class=\"bottom-bordered-cell right-bordered-cell center-aligned\">Fiber\/Filler Content in Elastomer Matrix, phr<\/th>\n<th class=\"bottom-bordered-cell center-aligned\">Linear Ablation Rate, mm\/s<\/th>\n<th class=\"bottom-bordered-cell center-aligned\">Reference<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">1. Nitrile rubber\u2013based HSM composite0\u00a0phr M. PI\/NBR<\/p>\n<p>2\u00a0phr M.PI\/NBR<\/p>\n<p>4\u00a0phr M.PI\/NBR<\/p>\n<p>6\u00a0phr M.PI\/NBR<\/p>\n<p>8\u00a0phr M.PI\/NBR<\/p>\n<p>6\u00a0phr Virgin polyimide\/NBR<\/p>\n<p>6\u00a0phr Virgin Kevlar\/NBR<\/td>\n<td class=\"center-aligned\">0.122<\/p>\n<p>0.064<\/p>\n<p>0.054<\/p>\n<p>0.050<\/p>\n<p>0.132<\/p>\n<p>0.132<\/p>\n<p>0.137<\/td>\n<td class=\"center-aligned\">65<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">2. Nitrile rubber\u2013based HSM compositeHNBR\/fumed silica<\/p>\n<p>HNBR\/organically modified montmorillonite<\/p>\n<p>HNBR\/expanded graphite<\/td>\n<td class=\"center-aligned\">0.063<\/p>\n<p>0.047<\/p>\n<p>0.067<\/td>\n<td class=\"center-aligned\">67<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">3. EPDM\u2010based HSM compositeWithout PSA\u2010pulp fiber \/EPDM<\/p>\n<p>With 10 phr untreated PSA pulp\/EPDM<\/p>\n<p>With 10 phr pretreated PSA pulp\/EPDM<\/td>\n<td class=\"center-aligned\">0.03\u00a0\u00b1\u00a00.001<\/p>\n<p>0.04\u00a0\u00b1\u00a00.001<\/p>\n<p>0.01\u00a0\u00b1\u00a00.001<\/td>\n<td class=\"center-aligned\">169<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">4. EPDM\u2010based HSM composite5\u00a0phr PSA\/EPDM<\/p>\n<p>10\u00a0phr PSA\/EPDM<\/p>\n<p>15\u00a0phr PSA\/EPDM<\/p>\n<p>20\u00a0phr PSA\/EPDM<\/p>\n<p>5\u00a0phr aramid\/EPDM<\/p>\n<p>10\u00a0phr aramid\/EPDM<\/p>\n<p>15\u00a0phr aramid\/EPDM<\/td>\n<td class=\"center-aligned\">0.015\u00a0\u00b1\u00a00.0001<\/p>\n<p>0.01\u00a0\u00b1\u00a00.0001<\/p>\n<p>0.02\u00a0\u00b1\u00a00.0001<\/p>\n<p>0.04\u00a0\u00b1\u00a00.0001<\/p>\n<p>0.02\u00a0\u00b1\u00a00.0001<\/p>\n<p>0.017\u00a0\u00b1\u00a00.0001<\/p>\n<p>0.03\u00a0\u00b1\u00a00.0001<\/td>\n<td class=\"center-aligned\">170<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">5. EPDM\u2010based HSM composite0\u00a0phr EPR\/EPDM<\/p>\n<p>5\u2003phr EPR\/EPDM<\/p>\n<p>10\u00a0phr EPR\/EPDM<\/p>\n<p>15\u00a0phr EPR\/EPDM<\/p>\n<p>20\u00a0phr EPR\/EPDM<\/td>\n<td class=\"center-aligned\">0.09<\/p>\n<p>0.065<\/p>\n<p>0.045<\/p>\n<p>0.047<\/p>\n<p>0.050<\/td>\n<td class=\"center-aligned\">171<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">6. EPDM\u2010based HSM composite0\u00a0phr M.PI\/EPDM<\/p>\n<p>2.5\u00a0phr M.PI\/EPDM<\/p>\n<p>5\u00a0phr M.PI\/EPDM<\/p>\n<p>10\u00a0phr M.PI\/EPDM<\/p>\n<p>Parent PI\/EPDM<\/p>\n<p>Parent kevlar\/EPDM<\/td>\n<td class=\"center-aligned\">0.20<\/p>\n<p>0.18<\/p>\n<p>0.06<\/p>\n<p>0.04<\/p>\n<p>0.06<\/p>\n<p>0.09<\/td>\n<td class=\"center-aligned\">168<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">7. Silicon\u2010based HSM composite0\u00a0phr ZrC\/silicon<\/p>\n<p>0\u00a0phr ZrO<sub>2<\/sub>\/silicon<\/p>\n<p>10\u00a0phr ZrC\/silicon<\/p>\n<p>10\u00a0phr ZrO<sub>2<\/sub>\/silicon<\/p>\n<p>20\u00a0phr ZrC\/silicon<\/p>\n<p>20\u00a0phr ZrO<sub>2<\/sub>\/silicon<\/p>\n<p>30\u00a0phr ZrC\/silicon<\/p>\n<p>30\u00a0phr ZrO<sub>2<\/sub>\/silicon<\/p>\n<p>40\u00a0phr ZrC\/silicon<\/p>\n<p>40\u00a0phr ZrO<sub>2<\/sub>\/silicon<\/td>\n<td class=\"center-aligned\">0.075<\/p>\n<p>0.075<\/p>\n<p>0.0725<\/p>\n<p>0.070<\/p>\n<p>0.0675<\/p>\n<p>0.065<\/p>\n<p>0.055<\/p>\n<p>0.045<\/p>\n<p>0.045<\/p>\n<p>0.02<\/td>\n<td class=\"center-aligned\">139<\/td>\n<\/tr>\n<tr>\n<td class=\"right-bordered-cell left-aligned\">8. Silicon rubber\u2013based HSMRTV control<\/p>\n<p>RTV\/APP<\/p>\n<p>RTV\/ADP<\/p>\n<p>RTV\/OPS<\/p>\n<p>RTV\/OPS\/APP<\/p>\n<p>RTV\/OPS\/ADP<\/td>\n<td class=\"center-aligned\">0.146\u00a0\u00b1\u00a00.004<\/p>\n<p>0.122\u00a0\u00b1\u00a00.005<\/p>\n<p>0.108\u00a0\u00b1\u00a00.001<\/p>\n<p>0.121\u00a0\u00b1\u00a00.003<\/p>\n<p>0.118\u00a0\u00b1\u00a00.004<\/p>\n<p>0.079\u00a0\u00b1\u00a00.004<\/td>\n<td class=\"center-aligned\">154<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n<div class=\"article-section__table-footnotes\">\n<ul>\n<li id=\"pat4101-note-0002\">Abbreviations: ADP, aluminum diethylphosphinate; APP, ammonium polyphosphate; EPDM, ethylene propylene diene monomer; HNBR, hydrogenated nitrile butadiene rubber; HSM, heat shielding material; M.PI, modified polyimide; NBR, nitrile butadiene rubber; OPS, octaphenyl polyhedral oligomeric silsesquioxane; PI, polyimide; PSA, polysulfonamide.<\/li>\n<li id=\"pat4101-note-0003\">Bolded figures denote the optimized composition from each EHSM.<\/li>\n<\/ul>\n<\/div>\n<\/div>\n<p>Zhang et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0154\" data-tab=\"pane-pcw-references\">154<\/a>\u00a0synthesized silicon rubber matrix incorporated with ammonium polyphosphate, aluminium diethylphosphinate, and octaphenyl polyhedral oligomeric silesquioxane composite and make out a highly flame retardant, ablative silicon rubber composite. Addition of flame retardants systemically improved the flame retardancy, thermal stability, smoke suppression, and thereby the linear ablation rate.<\/p>\n<\/div>\n<div id=\"pat4101-sec-0010\" class=\"article-section__sub-content\">\n<h3 class=\"article-section__sub-title section2\">6.4 Thermoplastic polyurethane\u2013based HSMs<\/h3>\n<p>Thermoplastic polyurethane nanocomposites are recommended to substitute for the popular EPDM composites in the contemporary state of art TPSs.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0155\" data-tab=\"pane-pcw-references\">155<\/a>\u00a0Thermoplastic polyurethane elastomer is created by the polyaddition reaction of polyol\/long chain diol, a chain extender or short chain diol, and a diisocyanate component.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0156\" data-tab=\"pane-pcw-references\">156<\/a>\u00a0Figure\u00a0<a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-fig-0007\">7<\/a>\u00a0indicates, the chemical structure of thermoplastic urethane formed from the polyol and diisocyanate in the presence of a chain extender. Thermoplastic polyurethane elastomer nanocomposites are the best choice of insulation material developed by Air Force Research Laboratory (AFRL) having lightweight, better ablation, good insulation features, and more cost effective fabricating method compared with the contemporary material, Kevlar\u2010filled EPDM.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0157\" data-tab=\"pane-pcw-references\">157<\/a><\/p>\n<section class=\"article-section__inline-figure\">\n<figure id=\"pat4101-fig-0007\" class=\"figure\"><source srcset=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/d0268490-9935-4230-bc0e-2042a35aa9e9\/pat4101-fig-0007-m.jpg\" media=\"(min-width: 1650px)\" \/><a href=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/d0268490-9935-4230-bc0e-2042a35aa9e9\/pat4101-fig-0007-m.jpg\" target=\"_blank\" rel=\"noopener noreferrer\"><img class=\"figure__image\" src=\"https:\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/db85c5dd-4086-4640-915d-266312675cb2\/pat4101-fig-0007-m.png\" alt=\"\" data-lg-src=\"\/\/wol-prod-cdn.literatumonline.com\/cms\/attachment\/d0268490-9935-4230-bc0e-2042a35aa9e9\/pat4101-fig-0007-m.jpg\" \/><\/a><figcaption class=\"figure__caption\">\n<div class=\"figure__caption__header\"><strong class=\"figure-title\">Figure 7<\/strong><\/p>\n<div class=\"figure-extra\"><a class=\"open-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#\">Open in figure viewer<\/a><a class=\"ppt-figure-link\" href=\"https:\/\/onlinelibrary.wiley.com\/action\/downloadFigures?id=pat4101-fig-0007&amp;doi=10.1002%2Fpat.4101\">PowerPoint<\/a><\/div>\n<\/div>\n<div>Structure of thermoplastic polyurethane [Colour figure can be viewed at\u00a0<a class=\"linkBehavior\" href=\"http:\/\/wileyonlinelibrary.com\/\">wileyonlinelibrary.com<\/a>]<\/div>\n<\/figcaption><\/figure>\n<\/section>\n<p>Since CNTs are well\u2010known fillers owed to their large aspect ratio and outstanding mechanical, thermal, and electrical properties,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0157\" data-tab=\"pane-pcw-references\">157<\/a>,\u00a0<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0158\" data-tab=\"pane-pcw-references\">158<\/a>\u00a0recently, Pircheraghi et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0159\" data-tab=\"pane-pcw-references\">159<\/a>prepared TPU\/CNT composite with enhanced properties. In the soft segment of TPU, CNT gets well dispersed,<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0160\" data-tab=\"pane-pcw-references\">160<\/a>\u00a0confirmed by the ultraviolet absorbance.<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0161\" data-tab=\"pane-pcw-references\">161<\/a>\u00a0By regulating the sonication speed and filler dispersion, thermal conductivity of the obtained composite can be effectively reduced.<\/p>\n<p>Jiao et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0162\" data-tab=\"pane-pcw-references\">162<\/a>\u00a0discussed about the collaborating flame decelerating and smoke annihilation effects of ferrous powder and ammonium polyphosphate in TPU matrix. Thermogravimetry (TG) and derivative TG results revealed that ferrous powder can minimize the decomposition temperature and can enhance the thermal stability and flame retardancy at larger temperatures. Lee et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0163\" data-tab=\"pane-pcw-references\">163<\/a>\u00a0studied the ablative properties of TPU elastomer with different nano reinforcements and concluded that multiwalled CNT composite is a good choice of ablative reinforcement, whereas carbon nanofiber is not an ideal ablative material. Jaramillo et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0164\" data-tab=\"pane-pcw-references\">164<\/a>\u00a0put an effort to optimize the formulation of TPU as an EHSM in an SRM along with other EHSMs.<\/p>\n<p>Liu et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0165\" data-tab=\"pane-pcw-references\">165<\/a>\u00a0compare the mechanical and flame retardancy properties of the polyoxymethylene (POM) with melamine phosphate and TPU\u2010encapsulated melamine phosphate\/POM. Analysis showed that POM\/TPU\u2010wrapped melamine phosphate has the most preferable thermal resistance and least formaldehyde release rate, favoring to the future applications. Maucourt et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0166\" data-tab=\"pane-pcw-references\">166<\/a>\u00a0patented for hydroxyl\u2010terminated polybutaduiene\/isophorone diisocyanate\u2013based polyurethane composition for inner surface coating of propulsion unit. Allcorn et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0056\" data-tab=\"pane-pcw-references\">56<\/a>\u00a0investigated the potential of TPU elastomeric nanocomposite as HSMs and concluded that they can be effectively used as HSMs for SRM with the inclusion of the special additives and fillers.<\/p>\n<p>Currently, Chen et al<a class=\"bibLink tab-link\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-bib-0167\" data-tab=\"pane-pcw-references\">167<\/a>\u00a0discussed about the synergistic effect of iron\u2010graphene and ammonium polyphosphate in TPU. Composite was prepared by solution\u2010blended master batch of TPU with iron\u2010graphene, finally melt blending of ammonium polyphosphate. Thermogravimetry and TG\u2010infrared data revealed that a highly thermally stable composite is obtained by this synergistic combination. All the ongoing research programs confer that TPU elastomer nanocomposites are an excellent choice of HSM in the nearby future.<\/p>\n<\/div>\n<\/div>\n<div id=\"pat4101-sec-0011\" class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0011-title\" class=\"article-section__title section__title section1\">7 A COMPARATIVE STUDY OF DIFFERENT EHSMS<\/h2>\n<p>Table\u00a0<a class=\"tableLink scrollableLink\" title=\"Link to table\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-tbl-0004\">4<\/a>\u00a0shows the ablation rates of different EHSMs observed in significant literatures causative to the insulation of SRM. The given data compare the ablation rates of various elastomeric composites at different fiber loading rate, pointing that optimizing the rate of suitable fiber loadings in an elastomer\u2010based HSM shows tremendous changes in the ablation rate. Studying the different composite ratios of significant elastomers, it is observable that manipulating the elastomers with different filler\/fiber loadings in each composition (from Table\u00a0<a class=\"tableLink scrollableLink\" title=\"Link to table\" href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101#pat4101-tbl-0004\">4<\/a>) gets optimized in each formulation. An ideal ablating composite will be the composite with low ablation rate and high ablation resistance. Even though their specific formulation is optimized with low ablation rates for better thermal stability of SRM in harsh environments, their mechanical properties need to be satisfied for their future applications as HSM for rocket motor casing applications. While dealing with the specific mechanical parameters such as low specific gravity and better aging properties, EPDM can be the reliable option for EHSM in SRM.<\/p>\n<\/div>\n<div id=\"pat4101-sec-0012\" class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0012-title\" class=\"article-section__title section__title section1\">8 CONCLUSION<\/h2>\n<p>In this review paper, various types of EHSMs were discussed as feasible candidates for SRM insulation and their fulfillment in practical applications. This review also includes the materials that could find application in the coming future, due to its properties like higher thermal stability and ablation characteristics. In the past decades, around 90% of heat shielding application in the SRMs were based on nitrile rubbers. Although space exploration missions beyond earth&#8217;s orbit are ready to equip with more temperature resistant and lightweight heat shielding ablative materials. The elastomers would be the better option among different polymeric ablatives with the figuration of suitable choice of fillers. The appropriate selection of fillers, reinforcements, and additives can modify the properties of shielding composite materials to a certain extent. Elastomeric composites fabricated with nanosized stiffening agents, advances to the new prototype for polymeric ablative materials.<\/p>\n<p>Nowadays, elastomeric materials like silicon, EPDM, and TPU elastomeric composites provide greater contributions as TPSs in the hypersonic flight missions. In addition to it, the highly fabricated asbestos fibers as reinforcements in the EHSMs can be replaced with aramid fibers, CNTs, and with PI fibers. A composite with low ablation rate can dramatically influence the insulation properties at the same time; good mechanical properties of the composite is mandatory. Advancements in these materials can be obtained by adjusting the reinforcement concentration, incorporation of multiple additives, optimal fiber loading percentage, and suitable processing techniques. In conclusion, propagating need for HSMs in the rocket industry successfully can be satisfied by the EHSMs. They are the most reliable candidates to replace metals and ceramic ablatives in the rocket aerospace reentry missions. Hence, by upgrading to the new elastomeric formulation with vulnerable reinforcements such as aramid fibers and PI fibers, there would be a tremendous change in the arena of rocket motor insulation. Ethylene propylene diene monomer with low specific gravity and better aging characteristics would be the most vulnerable choice of elastomers in SRM insulation. Fabricating new EPDM composite formulations with pretreated fillers using the conventional flame retardants, antioxidants, and adaptable reinforcements, there would be a dramatical progress in the rocket motor industry. While considering the environmental impact of these materials, proper agenda must be bore to develop an environmentally sustainable EHSM formulation to meet the requirements of SRM insulation with the existing or newly framed reinforcements or fillers with EPDM. Therefore, the future of rocket motor industry lies with EPDM elastomers.<\/p>\n<\/div>\n<div class=\"article-section__content\">\n<h2 id=\"pat4101-sec-0013-title\" class=\"article-section__title section__title section1\">ACKNOWLEDGEMENTS<\/h2>\n<p>The authors gratefully acknowledge the R&amp;D board (Grant Number: ARDB\/01\/1041841\/M\/1), Aeronautics wing of Defence Research and Development Organization (DRDO) for their support and funding.<\/p>\n<\/div>\n<p align=\"JUSTIFY\"><strong>Fuente:\u00a0<\/strong><em><a href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/pat.4101\" target=\"_blank\" rel=\"noopener noreferrer\">https:\/\/onlinelibrary.wiley.com<\/a><\/em><\/p>\n","protected":false},"excerpt":{"rendered":"<p>La posibilidad de que se produzca una ruptura catastr\u00f3fica durante el vuelo de cohetes y misiles exige una investigaci\u00f3n focalizada en el aislamiento de los&hellip; <\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[29,24],"tags":[],"_links":{"self":[{"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/posts\/3336"}],"collection":[{"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=3336"}],"version-history":[{"count":0,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=\/wp\/v2\/posts\/3336\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=3336"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=3336"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.fie.undef.edu.ar\/ceptm\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=3336"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}